It is used in industrial adhesive formulations in particular nontoluene formulation. Sds of methylcyclohexane, safety data sheets, cas 108872. Jan 10, 2014 scientific american is the essential guide to the most aweinspiring advances in science and. This chemical inventory is oshas premier onestop shop for occupational chemical information. Adhesives and sealant chemicals,fuels and fuel additives,functional fluids closed systems,solvents which become part of product formulation or mixture. Structure, properties, spectra, suppliers and links for. And it is also used for rubber, paint, varnish solvent, grease extraction solvent, etc. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. What are the causes of 4methylcyclohexane methanol poisoning. Methylcyclohexane is an organic compound with the molecular formula is ch 3 c 6 h 11. Identification of the substancemixture and of the companyundertaking. There is no warranty of accuracy or completeness of any information contained herein.
Extreme high moderate low section 1 chemical product and company identification. Articles of methyl cyclohexane are included as well. Determination of 4methylcyclohexyl methanol isomers by heated. The source is also providing more information like the publication year, authors and more. Sigmaaldrich offers sigmaaldrich398241, cyclohexanone for your research needs. Cyclohexane is cycloparaffinic hydrocarbon containing 6 carbons. Include all intermediates, formal charges and correct arrow pushing of electrons. Which of the following conditions would change the outcome of this reaction by promoting the production of 3methylhexene as the major product.
Application of gas chromatography with mass spectrometric and human olfactory sniffer detectors reveals the nature of odorous chemicals from an industrial chemical spill. Health effects for chemicals in 2014 west virginia. The river is the main water supply for over 300,000 residents in 8 counties. This study aimed to assess the toxicity of methylcyclohexane, a substance often used in rubber adhesives, ink and paint diluents, and cleansing agents. Kanawha valley customers, charleston, wv usa, downloaded at. Information collected included material safety data sheets sds provided to. Scientific american is the essential guide to the most aweinspiring advances in science and. Dangerous fire hazard when exposed to heat, flame, or oxidizersthe vapour is heavier than air and may travel along the ground.
Avoid long storage periods since the product is subject to degradation with age and may become more dangerous or hazardous. They were analyzed as is for metabolites or treated with glucuronidase and sulfatase first. It is colorless liquid, fast evaporation and high solvency power. Collect recoverable product into labeled containers for recycling. Methylcyclohexane is used in organic synthesis and as a solvent for cellulose ethers. Safety data sheet according to federal register vol. Mmchm 4methoxymethyl cyclohexane methanol cas 98955272 this study msds material safety data sheet nlm us national library of medicine. It may also be used as the starting material to synthesize 1methylcyclohexanecarbox ylic acid.
When absorbed by the human body for a long period or at a high dose, methylcyclohexane irritates eyes. Elizabeth scharman because it hasnt been adequately studied. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Safety evaluation of certain food additives and contaminants pdf. Issued a 14 day drinking water screening level for 4mchm for the. In the yeast library, 4mchm mainly induced chemical stress related to. P271 use only outdoors or in a wellventilated area. Section 1 chemical product and company identification. Chemical properties of 1chloro1methylcyclohexane cas 931. Toxicity assessment of 4methyl1cyclohexanemethanol and its. According to the eastman safety data sheet eastman chemical co, 2015, crude mchm contains only 6888% mchm while according to. Thats where 4methylcyclohexane methanol, mchm for short, comes in. When cis1bromo2 methylcyclohexane is treated with methanol and heat, four different products are formedtwo by substitution and two by elimination. Our msds sheets are based only on data available at the time of shipping and are subject to change without notice as new information is obtained.
Find more compounds similar to 1chloro1methylcyclohexane. Crude 4methylcyclohexane methanol 4mchm spilled in a river and then contaminated drinking water and air for over 300000 consumers living in west virginia. Methylcyclohexane is also used in some correction fluids such as whiteout as a. How dangerous is the chemical spilled into west virginia waters. Pdf dehydrogenation of methylcyclohexane for onboard. Methanol safety data sheet according to federal register vol. Do not attempt to extinguish fire unless flow of material can be stopped first. Now methylcyclohexane is widely used in many field. When absorbed by the human body for a long period or at a high dose, methylcyclohexane irritates eyes as well as the mucosa and upper respiratory tract. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.
Dehydrogenation of methylcyclohexane for onboard hydrogen use. Methylcyclohexane msds search our sds online database free. Hello rchemistry, i live in the charleston, wv area, and currently, 8 counties are in a state or emergency due to a leak of 4methylcyclohexane methanol, a chemical used to clean mining equipment. Rosen3 1 professor, utah state university 2 assistant professor, university of south alabama 3president, corona environmental consulting march 17, 2014 ver. Chemical identification and physical properties exposure limits sampling information. Dehydrogenation of methylcyclohexane for onboard hydrogen. Take the time to validate and double check the source of the data. Complexities of human odor perception for cis and trans4methylcyclohexane methanol from the chemical spill in west virginia. Classified as saturated hydrocarbon, it is a colourless liquid with a faint odor. They were analyzed as is for metabolites or treated with. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Chemical properties of 1chloro1methylcyclohexane cas. Health effects for chemicals in 2014 west virginia chemical.
Move container from fire area if it can be done without risk. Use only spark free shovels and explosion proof equipment. Page 1 of 10 material safety data sheet methanol product name methanol ch 3oh synonyms alcohol, methyl hydroxide, methyl hydrate, wood alcohol, wood spirit product use solvent, fuel, feedstock company identification methanol holdings trinidad limited atlantic avenue, point lisas industrial estate. Jan 10, 2014 little is known about the safety implications for 4 methylcyclohexane methanol, according to the states poison control director dr. Issuu is a digital publishing platform that makes it simple to publish magazines, catalogs, newspapers, books, and more online. Mar 05, 2018 what are the causes of 4methylcyclohexane methanol poisoning. Toxicity of methylcyclohexane and its effect on the. Aug 14, 2015 issuu is a digital publishing platform that makes it simple to publish magazines, catalogs, newspapers, books, and more online.
Eastman chemical companys msds for crude unpurified mchm, as supplied by npr, reports an oral ld50 of. A wide variety of methylcyclohexane options are available to you, there are 117 suppliers who sells methylcyclohexane on, mainly located in asia. Find product specific information including structure, price, uses, cas, msds, protocols and references. Provide a step by step mechanism for the formation of the above products. Osha occupational chemical database occupational safety. If water is used for cooling, the solution will spread if not contained. Easily share your publications and get them in front of issuus. It is mainly converted in naphtha reformers to toluene. Vaporphase 4methylcyclohexanemethanol will be degraded in the atmosphere by reaction with photochemicallyproduced hydroxyl radicals. It compiles information from several government agencies and organizations. A west virginia chemical spill, which has cut off water to hundreds of thousands of citizens across nine counties in the state. Absorb remaining product with sand, earth or vermiculite. A west virginia chemical spill, which has cut off water to hundreds of thousands of citizens across nine. How dangerous is the chemical spilled into west virginia.
Show this material safety data sheet to the doctor in attendance. Health effects for chemicals in 2014 west virginia chemical release. Little is known about the safety implications for 4methylcyclohexane methanol, according to the states poison control director dr. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is.
Prolonged exposure to high concentrations of 4 methylcyclohexane methanol can cause headaches, eye and skin irritation, and. P270 do not eat, drink or smoke when using this product. Extreme high moderate low section 1 chemical product and company identification product name. Exposure to 4methylcyclohexane methanol usually takes place through contaminated water that affects ones skin andor eyes.
Chemeo is only indexing the data, follow the source links to retrieve the latest data. Hello rchemistry, i live in the charleston, wv area, and currently, 8 counties are in a state or emergency due to a leak of 4 methylcyclohexane methanol, a chemical used to clean mining equipment. Sep 30, 2011 this study aimed to assess the toxicity of methylcyclohexane, a substance often used in rubber adhesives, ink and paint diluents, and cleansing agents. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Mixtures of methanol and water at concentrations greater than 20% methanol are still considered flammable.
Buy 3methylcyclohexane1,2dione cas 3008433, a biochemical for proteomics research, from santa cruz. The metabolism of methylcyclohexane was studied in rats. Evaluation of 4methylcyclohexanemethanol mchm in a combined. Immediately flush with plenty of water for at least 15 minutes, if easy to do, remove contact lenses.
Sep, 2014 register now and get a free online msds binder. Methylcyclohexane may be used as a solvent for the synthesis of unsolvated nbutylmagnesium chloride by the reaction of 1chlorobutane with magnesium powder. Osha occupational chemical database occupational safety and. Other uses for cyclohexane include various solvent applications and the production of cyclohexanol and cyclohexanone. Urine samples were collected during the first 48 hr of dosing.